Institute of Inorganic Chemistry (Spingler Group) Publications

 

 

2010

2009

2008

2007

2006

2005

2004

2003

2002

2001

2000-1996


2010

79.

Preparation and biological evaluation of cyclopentadienyl based 99mTc-complexes [(Cp-R)99mTc(CO)3] mimicking benzamides for malignant melanoma targeting

H. W. Peindy N’Dongo, P. D. Raposinho, C. Fernandes, I. Santos, D. Can, P. Schmutz, B. Spingler, R. Alberto* Nuc. Med. Biol. 2010, in press.

78.

High yield synthesis and crystal structure determination of sodium triphenylphosphine monosulfonate (TPPMSNa)

A. Karschin, W. Kläui*, W. Peters, B. Spingler Eur. J. Inorg. Chem. 2010, 942–946.

77.

Can copper(II) mediate Hoogsteen base-pairing in a left-handed DNA duplex? A pulse EPR study

M. G. Santangelo, P. M. Antoni, B. Spingler*, G. Jeschke* ChemPhysChem 2010, 599–606.

76.

Triazacyclohexane (tach) Complexes of High-Valent Rhenium: Syntheses of [(R3tach)ReO3] (R = -CH3, -CH2C6H5) and Its Substitution Reactions

H. Braband, S. Imstepf, M. Felber, B. Spingler, R. Alberto* Inorg. Chem. 2010, 49, 1283–1285.

2009

75.

Tricarbonylmanganese and -rhenium Complexes of Imidazol-Based Phosphane Ligands: Influence of the Substitution Pattern on the CO Release Properties

P. C. Kunz*, W. Huber, A. Rojas, U. Schatzschneider, B. Spingler Eur. J. Inorg. Chem. 2009, 5358–5366.

74.

Imidazole-based phosphane gold(I) complexes as potential agents for cancer treatment: Synthesis, structural studies and antitumour activity

P. C. Kunz*, M. U. Kassack, A. Hamacher, B. Spingler Dalton Trans. 2009, 7741–7747.

73.

Synthesis and Reactivity of the 17 e- Complex [ReIIBr4(CO)2]2-: A Convenient Entry into Rhenium(II) Chemistry

F. Zobi, L. Kromer, B. Spingler, R. Alberto* Inorg. Chem. 2009, 48, 8965–8970.

72.

Caesium-templated lanthanoid-containing polyoxotungstates

F. Hussain, B. Spingler, F. Conrad, M. Speldrich, P. Kögerler, C. Boskovicc, G. R. Patzke* Dalton Trans. 2009, 4423–4425.

71.

Interaction of Novel Metal Complexes with DNA: Synthetic and Structural Aspects

B. Spingler*, C. Da Pieve, A. Medina-Molner, P. M. Antoni, M. G. Santangelo Chimia 2009, 63, 153–156.

70.

Functionalised Tris(pyrazolyl)methane Ligands and Re(CO)3 Complexes Thereof

P. C. Kunz*, M. Berghahn, N. E. Brückmann, M. Dickmeis, M. Kettel, B. Spingler Z. Anorg. Allg. Chem. 2009, 635, 471–478.

69.

Aqueous syntheses of [(Cp-R)M(CO)3] type complexes (Cp = cyclopentadienyl, M = Mn, 99mTc, Re) with bioactive functionalities

H.W. Peindy N’Dongo, Y. Liu, D. Can, P. Schmutz, B. Spingler, R. Alberto* J. Organomet. Chem. 2009, 694, 981–987.

68.

Hydrothermal Strategies Towards Polyoxofluoromolybdates(VI)

A. Michailovski, F. Hussain, B. Spingler, J. Wagler, G. R. Patzke* Cryst. Growth Des. 2009, 9, 755–765.

2008

67.

Substitution reactions with [ReBr2(CO)2(NCCH3)2]-: a convenient route to complexes with the cis-[Re(CO)2]+ core

L. Kromer, B. Spingler, R. Alberto* Dalton Trans. 2008, 5800–5806.

66.

Ligand-mediated decarbonylation as an efficient synthetic method to Re(I) and Re(II) dicarbonyl complexes

F. Zobi*, B. Spingler, R. Alberto Dalton Trans. 2008, 5287–5289.

65.

Syntheses, Structures and Reactivities of [CpTc(CO)3X]+ and [CpRe(CO)3X]+

F. Zobi, B. Spingler, R. Alberto* Eur. J. Inorg. Chem. 2008, 4205–4214.

Publication selected for the cover illustration.

64.

“Click-to-Chelate”: Design and Incorporation of Triazole Containing Metal Chelating Systems into Biomolecules of Diagnostic and Therapeutic Interest

H. Struthers, B. Spingler, T. L. Mindt, R. Schibli* Chem. Eur. J. 2008, 14, 6173-6183.

63.

Derivatives of Sodium Boranocarbonate as Novel CO-Releasing Molecules (CO-RMs)

T. S. Pitchumony, B. Spingler, R. Motterlini, R. Alberto* Chimia 2008, 62, 277-279.

62.

Syntheses and characterization of vitamin B12–Pt(II) conjugates and their adenosylation in an enzymatic assay

P. Ruiz-Sánchez, S. Mundwiler, B. Spingler, N. R. Buan, J. C. Escalante-Semerena, R. Alberto* J. Biol. Inorg. Chem. 2008, 13, 335-347.

61.

Metal-Mediated Retro Diels-Alder of Dicyclopentadiene Derivatives: A Convenient Synthesis of [(Cp-R)M(CO)3] (M = 99mTc, Re) Complexes

Y. Liu, B. Spingler, P. Schmutz, R. Alberto* J. Am. Chem. Soc. 2008, 129, 1554-1555.

60.

High-Valent Technetium Complexes with the [99TcO3]+ Core from in Situ Prepared Mixed Anhydrides of [99TcO4]- and Their Reactivities

Y. Tooyama, H. Braband, B. Spingler, U. Abram, R. Alberto* Inorg. Chem. 2008, 47, 257-264.

2007

59.

The Synthesis of 1,2-Bis(1,5,9-triazacyclododecyl)ethane: A Showcase for the Importance of the Linker Length within Bis(alkylating) Reagents

A. Medina-Molner, O. Blacque, B. Spingler* Org. Lett. 2007, 9, 4829-4831.

58.

Attempted Abstraction of the Halogenides in (HNEt3)[Re(CH3CN)2Cl4] and Crystal Structures of cis-[Re(CH3CN)2Cl4]·CH3CN and cis-[Re(NHC(OCH3)-CH3)2Cl4]

P. C. Kunz*, P. Kurz, B. Spingler, R. Alberto Z. Anorg. Allg. Chem. 2007, 633, 2753-2756.

57.

Structural Analysis of Cu(II) Ligation to the 5’-GMP Nucleotide by Pulse EPR Spectroscopy

M. G. Santangelo, A. Medina-Molner, A. Schweiger (†), G. Mitrikas*, B. Spingler* J. Biol. Inorg. Chem. 2007, 12, 767-775.

56.

To be Dinuclear or not: Z-DNA Induction by Nickel Complexes

B. Spingler* , P. M. Antoni Chem. Eur. J. 2007, 6617-6622.

55.

Structures of b- and d-Acid Derivatives of Vitamin B12 and Their Complexes with [M(CO)3]+ (M = 99mTc, Re)

B. Spingler, S. Mundwiler, P. Ruiz-Sánchez, D. R. van Staveren, R. Alberto* Eur. J. Inorg. Chem. 2007, 2641-2647.

54.

Cell Specific and Nuclear Targeting with [M(CO)3]+ (M = 99mTc, Re) Based Complexes Conjugated to Acridine Orange and Bombesin

N. Agorastos, L. Borsig, A. Renard, P. M. Antoni, G. Viola, B. Spingler, P. Kurz, R. Alberto* Chem. Eur. J. 2007, 3842-3852.

53.

Efficient Routes for the Synthesis of 1,4,7,10,13-Pentaazacyclohexa-decan-14-16-dione

C. Da Pieve, A. Medina-Molner, B. Spingler* Synthesis 2007, 679-682.

52.

Synthesis and reactivity of [ReBr2(NCCH3)2(CO)2]-: A new precursor for bioorganometallic chemistry

L. Kromer, B. Spingler, R. Alberto* J. Organomet. Chem. 2007, 692, 1372-1376.

51.

Iodination of cisplatin adduct of Vitamin B12 [{B12}-CN-{cis-PtCl(NH3)2}]+

P. Ruiz-Sánchez, S. Mundwiler, A. Medina-Molner, B. Spingler, R. Alberto* J. Organomet. Chem. 2007, 692, 1358-1362.

50.

Towards Polymer Diagnostics - Copolymers of N-(2-hydroxypropyl)methacryl-amide and bis(2-pyridylmethyl)-4-vinylbenzylamine: Synthesis, Characterisation and Re(CO)3-Labeling

P. C. Kunz*, N. E. Brückmann, B. Spingler Eur. J. Inorg. Chem. 2007, 394-399.

49.

Tricarbonyl[tris(pyrazol-1-yl)methanesulfonato-k3N,N´,N´´]rhenium(I) acetone solvate

P. C. Kunz*, P. Kurz, B. Spingler, R. Alberto Acta Cryst. 2007, E63, m363–m364.

2006

48.

Very Small and Soft Scorpionates: Water Stable Technetium Tricarbonyl Complexes Combining a Bis-agostic (k3-H, H, S) Binding Motif with Pendant and Integrated Bioactive Molecules

L. Maria, A. Paulo, I. C. Santos, I. Santos, P. Kurz, B. Spingler, R. Alberto* J. Am. Chem. Soc. 2006, 128, 14590-14598.

47.

Ligand Variations in [ReX(diimine)(CO)3] Complexes: Effects on Photocatalytic CO2 Reduction

P. Kurz, B. Probst, B. Spingler, R. Alberto* Eur. J. Inorg. Chem. 2006, 2966-2974.

2005

46.

Interaction of Mono- and Dinuclear Metal Complexes with Mono- and Oligonucleotides for Analytical, Radio- and Chemotoxic Purposes

B. Spingler, F. Zobi, P. M. Antoni, A. Medina-Molner, R. Alberto* Chimia 2005, 59, 826-831.

45.

Guanine and plasmid DNA binding of mono- and trinuclear fac-[Re(CO)3]+ complexes with amino acid Ligands

F. Zobi, B. Spingler, R. Alberto* ChemBioChem. 2005, 6, 1397-1405.

44.

Comparative studies of substitution reactions of rhenium(I) dicarbonyl-nitrosyl and tricarbonyl complexes in aqueous media

N. Marti, B. Spingler, F. Breher, R. Schibli* Inorg. Chem. 2005, 44, 6082-6091.

43.

Structure, reactivity and solution behaviour of [Re(ser)(7-MeG)(CO)3] and [Re(ser)(3-pic)(CO)3]: "nucleoside-mimicking" complexes based on the fac-[Re(CO)3]+ moiety

F. Zobi, B. Spingler, R. Alberto* Dalton Trans. 2005, 2859-2865.

42.

Picolylamine-methylphosphonic acid esters as tridentate ligands for the labeling of alcohols with the fac-[M(CO)3]+ core (M=99mTc, Re): synthesis and biodistribution of model compounds and of a 99mTc-labeled cobinamide

S. Mundwiler, R. Waibel, B. Spingler, S. Kunze, R. Alberto* Nucl. Med. Biol. 2005, 32, 473-484.

41.

Cyanide-bridged vitamin B-12-cisplatin conjugates

S. Mundwiler, B. Spingler, P. Kurz, S. Kunze, R. Alberto* Chem. Eur. J. 2005, 11, 4089-4095.

40.

Induction of B- to Z-DNA transition by copper and zinc complexes with C(15) substituted macrocyclic pentaaza ligands

B. Spingler*, C. Da Pieve Dalton Trans. 2005, 1637-1643.

39.

Functionalization of Glucose at Position C-3 for Transition Metal Coordination: Organo-Rhenium Complexes with Carbohydrate Skeletons

C. Dumas, J. Petrig, L. Frei, B. Spingler, R. Schibli* Bioconjugate Chem., 2005, 16, 421 - 428.

38.

Structure, stability, and biodistribution of cationic [M(CO)3]+ (M = Re, 99Tc, 99mTc) complexes with tridentate amine ligands

P. Häfliger, S. Mundwiler, K. Ortner, B. Spingler, R. Alberto*, G. Andocs, L. Balogh, K. Bodo Synth. React. Inorg. Met.-Org. Chem. 2005, 35, 27-34.

37.

Anions or cations: Who is in charge of inhibiting the nickel(II) promoted B- to Z-DNA transition?

B. Spingler* Inorg. Chem. 2005, 44, 831-833.

36.

The chemistry of the fac-[Re(CO)2(NO)]2+ fragment in aqueous solution

P. Kurz, D. Rattat, D. Angst, H. Schmalle, B. Spingler, R. Alberto*, H. Berke*, W. Beck Dalton Trans. 2005, 804 - 810.

35.

Syntheses and Characterization of Dicarbonyl-Nitrosyl Complexes of Technetium(I) and Rhenium(I) in Aqueous Media: Spectroscopic, Structural, and DFT Analyses

R. Schibli*, N. Marti, P. Maurer, B. Spingler, M.-L. Lehaire, V. Gramlich, Ch. L. Barnes Inorg. Chem. 2005, 44, 683 - 690.

34.

Induction of DNA-Double-Strand Breaks by Auger Electrons from 99mTc Complexes with DNA-Binding Ligands

P. Häfliger, N. Agorastos, B. Spingler, O. Georgiev, G. Viola, R. Alberto* ChemBioChem 2005, 6, 414 - 421.

2004

33.

Conjugation of a novel histidine derivative to biomolecules and labelling with [99mTc(OH2)3(CO)3]+

D. R. Van Staveren, S. Mundwiler, U. Hoffmanns, J. K. Pak, B. Spingler, N. Metzler-Nolte, R. Alberto* Org. Biomol. Chem. 2004, 2, 2593-2603.

32. 

Vitamin B12 as a Ligand for Technetium and Rhenium Complexes

S. Kunze, F. Zobi, P. Kurz, B. Spingler, R. Alberto* Angew. Chem. Int. Ed. 2004, 43, 5025-5029.

31.

[TcI(CN)3(CO)3]2- and [TcI(CN)3(CO)3]2-: Case Studies for the Binding Properties of CN- and CO

P. Kurz, B. Spingler, T. Fox, R. Alberto* Inorg. Chem. 2004, 43, 3789-3791.

30.

Direct synthesis of tricarbonyl(cyclopentadienyl)rhenium and tricarbonyl(cyclo-pentadienyl)technetium units from ferrocenyl moieties - Preparation of 17-α-ethynylestradiol derivatives bearing a tricarbonyl (cyclopentadienyl) technetium group

S. Masi, S. Top*, L. Boubekeur, G. Jaouen*, S. Mundwiler, B. Spingler, R. Alberto* Eur. J. Inorg. Chem. 2004, 2013-2017.

29.

Head-to-Head (HH) and Head-to-Tail (HT) Conformers of cis-Bis Guanine Ligands Bound to the [Re(CO)3]+ Core

F. Zobi, O. Blacque, H. W. Schmalle, B. Spingler, R. Alberto* Inorg. Chem. 2004, 43, 2087-2096.

28. 

Synthesis and Characterization of Cu2(I,I), Cu2(I,II), and Cu2(II,II) Compounds Supported by Two Phthalazine-Based Ligands: Dramatic Influence of a Hydrophobic Pocket

J. Kuzelka, S. Mukhopadhyay, B. Spingler, S. J. Lippard* Inorg. Chem. 2004, 43, 1751-1761.

2003

27.

Reactivity of 2-pyridine-aldehyde and 2-acetyl-pyridine coordinated to [Re(CO)3]+ with alcohols and amines: metal mediated Schiff base formation and dimerization

W. W. Wang, B. Spingler, R. Alberto* Inorg. Chim. Acta 2003, 355, 386-393.

26.

Modeling Features of the Non-Heme Diiron Cores in O2-Activating Enzymes through the Synthesis, Characterization, and Oxidation of 1,8-Naphthyridine-Based Complexes

J. Kuzelka, S. Mukhopadhyay, B. Spingler, S. J. Lippard* Inorg. Chem. 2003, 42, 6447-6457.

25.

Toward novel DNA binding metal complexes: Structure and basic kinetic data of [M(9-MeG)2(CH3OH)(CO)3]+ (M=99Tc, Re)

F. Zobi, B. Spingler, T. Fox, R. Alberto* Inorg. Chem. 2003, 42, 2818-2820.

24.

Nε Functionalization of Metal and Organic Protected L-Histidine for a Highly Efficient, Direct Labeling of Biomolecules with [Tc(OH2)3(CO)3]+

J. K. Pak, P. Benny, B. Spingler, K. Ortner, R. Alberto* Chem. Eur. J. 2003, 9, 2053-2061.

23.

Zinc-bound thiolate-disulfide exchange: A strategy for inhibiting metallo-β-lactamases

H. Boerzel, M. Koeckert, W. M. Bu, B. Spingler, S. J. Lippard* Inorg. Chem. 2003, 42, 1604-1615.

22.

Aqueous synthesis of derivatized cyclopentadienyl complexes of technetium and rhenium directed toward radiopharmaceutical application

J. Bernard, K. Ortner, B. Spingler, H. J. Pietzsch, R. Alberto* Inorg. Chem. 2003, 42, 1014-1022.

2002

21.

Synthesis and structure of [Fe13O4F24(OMe)12]5-: The first open-shelf Keggin ion

A. Bino, M. Ardon, D. Lee, B. Spingler, S. J. Lippard* J. Am. Chem. Soc. 2002, 124, 4578-4579

20.

Central vs. peripheral Ag(I) coordination in NS3-open chain and cage ligands

J. M. Baumeister, R. Alberto, K. Ortner, B. Spingler, P. A. Schubiger, T. A. Kaden* J. Chem. Soc., Dalton Trans. 2002, 4143-4151.

19.

Carboxylate-bridged diiron(II) complexes with a sterically hindered phthalazine ligand

J. Kuzelka, B. Spingler, S. J. Lippard* Inorg. Chim. Acta 2002, 337, 212-222.

18.

Sterically hindered carboxylate ligands support water-bridged dimetallic centers that model features of metallohydrolase active sites

D. Lee, P. L. Hung, B. Spingler, S. J. Lippard* Inorg. Chem. 2002, 41, 521-531. 

2001

17. 

Fluorescent sensors for Zn2+ based on a fluorescein platform: Synthesis, properties and intracellular distribution

S. C. Burdette, G. K. Walkup, B. Spingler, R. Y. Tsien, S. J. Lippard* J. Am. Chem. Soc. 2001, 123, 7831-7841.

16.

2.4 angstrom crystal structure of an oxaliplatin 1,2-d(GpG) intrastrand cross-link in a DNA dodecamer duplex

B. Spingler, D. A. Whittington, S. J. Lippard* Inorg. Chem. 2001, 40, 5596-5602.

15.

Synthesis and spectroscopic studies of non-heme diiron(III) species with a terminal hydroperoxide ligand: Models for hemerythrin

T. J. Mizoguchi, J. Kuzelka, B. Spingler, J. L. DuBois, R. M. Davydov, B. Hedman, K. O. Hodgson, S. J. Lippard* Inorg. Chem. 2001, 40, 4662-4673.

14.

Intermediate in β-lactam hydrolysis catalyzed by a dinuclear zinc(II) complex: Relevance to the mechanism of metallo-β-lactamase

N. V. Kaminskaia, B. Spingler, S. J. Lippard* J. Am. Chem. Soc. 2001, 123, 6555-6563.

13.

Pentacoordinate cobalt(III) thiolate and nitrosyl tropocoronand compounds

K. J. Franz, L. H. Doerrer, B. Spingler, S. J. Lippard* Inorg. Chem. 2001, 40, 3774-3780.

12.

Crystal structure determination of a (μ-amido)(μ-hydroxo)(μ-superoxo) dicobalt(III) complex from the Werner collection

B. Spingler, M. Scanavy-Grigorieff, A. Werner, H. Berke*, S. J. Lippard* Inorg. Chem. 2001, 40, 1065-1066.

11.

1,2-d(GpG) intrastrand cross-link formed by oxaliplatin with duplex DNA: a crystallographic study

B. Spingler, D. A. Whittington, S. J. Lippard* J. Inorg. Biochem. 2001, 86, 440-440.

2000 - 1996

10.

Hydrolysis of β-Lactam Antibiotics Catalyzed by Dinuclear Zinc(II) Complexes - Functional Mimics of Metallo-β-lactamases

N. V. Kaminskaia, B. Spingler, S. J. Lippard* J. Am. Chem. Soc. 2000, 122, 6411-6422.

9.

Monodentate-bridged phosphodiester and sulfate complexes: Structural insights into the biological activation of phosphodiesters, sulfate, and sulfate esters

C. He, V. Gomez, B. Spingler, S. J. Lippard* Inorg. Chem. 2000, 39, 4188-4189.

8.

Aminotroponiminates as ligands for potential metal-based nitric oxide sensors

K. J. Franz, N. Singh, B. Spingler, S. J. Lippard* Inorg. Chem. 2000, 39, 4081-4092.

7.

X-ray structure of a heterochiral, sulfoximine-stabilized dilithiomethane derivative

J. F. K. Müller*, M. Neuburger, B. Spingler Angew. Chem. Int. Ed. 1999, 38, 3549-3552.

6.

Chiral lithiated phosphoric triamides: Structure, reactivity, and salt effects

J. F. K. Müller*, M. Zehnder, F. Barbosa, B. Spingler Helv. Chim. Acta 1999, 82, 1486-1501.

5.

Structural investigation of a dilithiated phosphonate in the solid state

J. F. K. Müller*, M. Neuburger, B. Spingler Angew. Chem. Int. Ed. 1999, 38, 92-94.

4.

New chiral hypervalent iodine compounds in asymmetric synthesis

U. H. Hirt, B. Spingler, T. Wirth* J. Org. Chem. 1998, 63, 7674-7679.

3.

Synthesis and structure of a chiral bicyclic stannylated phosphoric triamide

B. Spingler, J. F. K. Müller*, M. Neuburger, M. Zehnder J. Organomet. Chem. 1998, 570, 293-296.

2.

Synthesis and Reactions of Chiral α-Lithiophosphoric Triamides

J. F. K. Müller*, B. Spingler, M. Zehnder Synlett 1997, 1059-1060.

1.

Synthesis and X-Ray Structure of  Bis{S-(1-lithio-3,3-diphenylprop-2-enyl)-N-methyl- S-phenylsulfoximine} *Tetrahydrofuran Complemented by Model ab initio Calculations of α-Lithiosulfoximines 

J. F. K. Müller*, R. Batra, B. Spingler, M. Zehnder Helv. Chim. Acta 1996, 79, 820-826.